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Beilstein J. Org. Chem. 2018, 14, 2250–2258, doi:10.3762/bjoc.14.200
Graphical Abstract
Figure 1: The structures of carbocyclic diazodiketones 1a–g and C–H-donating tetrahydrofuran used in the proj...
Figure 2: Molecular structure of hydrazone 2b as determined by X-ray analysis data (Olex2 plot with 50% proba...
Scheme 1: Photochemical cycloelimination of furans from hydrazones 2d,e.
Scheme 2: Different pathways of diazodiketones 1 light-induced reactions in the singlet (reaction I) and trip...
Beilstein J. Org. Chem. 2017, 13, 2569–2576, doi:10.3762/bjoc.13.253
Scheme 1: General scheme for intramolecular heterocylization of intermediate X-ylides.
Figure 1: Thioamides 1a–e, diazoesters 2a–d and Rh(II)-catalysts used in the project.
Figure 2: The structures of compounds 4a and 3b according to the data of X-ray analysis (Olex2 plot with 50% ...
Scheme 2: Rh(II)-Catalyzed reactions of α-diazocyanoacetic ester 2d with α-cyanothioacetamides 1a–e.
Figure 3: The structure of thiophene 5c according to the data of X-ray analysis (Olex2 plot with 50% probabil...
Scheme 3: Interaction of thioacetamide 1e with dirhodium pivalate to produce complex 6e.
Figure 4: The structure of the complex 6e according to the data of X-ray analysis (Olex2 plot with 50% probab...
Scheme 4: The assumed mechanism for the formation of thiophenes 3, 5.
Scheme 5: The plausible mechanism for the formation of thiophenes 4.
Beilstein J. Org. Chem. 2016, 12, 1904–1910, doi:10.3762/bjoc.12.180
Scheme 1: Catalytic reactions of diazocarbonyl compounds with unsaturated δ-amino esters.
Figure 1: The structures of the starting compounds 1–3 and catalysts used in this study.
Scheme 2: The assumed pathway for the occurance of amides 6a–c by way of the catalytic Wolff rearrangement.
Scheme 3: The assumed mechanism for the formation of the amides 4 and 7 during oxidative cleavage of the N–H-...